Effects of Manganese Addition on the Corrosion Behaviour of Aluminium Alloys in Different Media

Authors

  • N. E. Idenyi DEPARTMENT OF INDUSTRIAL PHYSICS, EBONYI STATE UNIVERSITY, ABAKALIKI EBONYI STATE, NIGERIA
  • P. A. Nwofe DEPARTMENT OF INDUSTRIAL PHYSICS, EBONYI STATE UNIVERSITY, ABAKALIKI EBONYI STATE, NIGERIA
  • P. E. Agbo DEPARTMENT OF INDUSTRIAL PHYSICS, EBONYI STATE UNIVERSITY, ABAKALIKI EBONYI STATE, NIGERIA
  • B. J. Ifeanyichukwu DEPARTMENT OF INDUSTRIAL PHYSICS, EBONYI STATE UNIVERSITY, ABAKALIKI EBONYI STATE, NIGERIA
  • O. C. Ozibo DEPARTMENT OF INDUSTRIAL PHYSICS, EBONYI STATE UNIVERSITY, ABAKALIKI EBONYI STATE, NIGERIA

Keywords:

Alloy, aluminum, corrosion, passivation

Abstract

In this paper, we report on the effect of manganese addition on  the corrosion behavior of aluminium alloys in some different media (H2SO4, hydrogen tetraoxosulphate (vi) and HCl, hydrochloric acid).  Aluminum alloys containing 1.5%, 2.5% and 3.5% manganese were  cast into rods; which were later machined and subsequently cut into coupons averaging a total surface area of 13.33cm3. The samples were weighed and immersed into beakers containing 0.25M, 0.5M, and 1.0M of H2SO4 and HCl solutions respectively. The set up were allowed to stand for 48 hours with the coupons removed every 12 hours for weight loss measurements using the normal procedures. The results show that the corrosion rate decreased with increasing exposure time in the respective media. In particular, at a concentration of 0.5 M H2SO4, a step decrease was observed, indicating the possibility of the precipitation of the intermetallic compounds and the amount of intermetallic precipitation increase arising from the manganese addition.

Author Biographies

  • N. E. Idenyi, DEPARTMENT OF INDUSTRIAL PHYSICS, EBONYI STATE UNIVERSITY, ABAKALIKI EBONYI STATE, NIGERIA

    DEPARTMENT OF INDUSTRIAL PHYSICS,
    EBONYI STATE UNIVERSITY,
    ABAKALIKI
    EBONYI STATE,
    NIGERIA

    Rank is Professor

  • P. A. Nwofe, DEPARTMENT OF INDUSTRIAL PHYSICS, EBONYI STATE UNIVERSITY, ABAKALIKI EBONYI STATE, NIGERIA

    DEPARTMENT OF INDUSTRIAL PHYSICS,
    EBONYI STATE UNIVERSITY,
    ABAKALIKI
    EBONYI STATE,
    NIGERIA

    Rank is Senior Lecturer

  • P. E. Agbo, DEPARTMENT OF INDUSTRIAL PHYSICS, EBONYI STATE UNIVERSITY, ABAKALIKI EBONYI STATE, NIGERIA

    DEPARTMENT OF INDUSTRIAL PHYSICS,
    EBONYI STATE UNIVERSITY,
    ABAKALIKI
    EBONYI STATE,
    NIGERIA

    Rank is Senior Lecturer

     

    Rank is Senior Lecturer

  • B. J. Ifeanyichukwu, DEPARTMENT OF INDUSTRIAL PHYSICS, EBONYI STATE UNIVERSITY, ABAKALIKI EBONYI STATE, NIGERIA
    DEPARTMENT OF INDUSTRIAL PHYSICS,
    EBONYI STATE UNIVERSITY,
    ABAKALIKI
    EBONYI STATE,
    NIGERIA
  • O. C. Ozibo, DEPARTMENT OF INDUSTRIAL PHYSICS, EBONYI STATE UNIVERSITY, ABAKALIKI EBONYI STATE, NIGERIA
    DEPARTMENT OF INDUSTRIAL PHYSICS,
    EBONYI STATE UNIVERSITY,
    ABAKALIKI
    EBONYI STATE,
    NIGERIA

References

A.M. Pardo, C. Merino, A. E. Coy, R. Arrabal, F. Viejo, and E. Matykina, "Corrosion behaviour of magnesium/aluminium alloys in 3.5 wt.% NaCl," Corrosion Science, vol. 50, no. 3, pp.823-834, 2008.

M. Zamin, "The role of Mn in the corrosion behavior of Al-Mn alloys," Corrosion, vol. 37, no. 11, pp. 627-632, 1981.

R. Rosliza, W.B. Wan Nik, and H. B. Senin, "The effect of inhibitor on the corrosion of aluminum alloys in acidic solutions," Materials Chemistry and Physics. vol. 107, no. 2, pp. 281-288, 2008.

U.R. Evans, The Corrosion and Oxidation of Metals, London, Edward Amold, 1976.

C.E. Ekuma, and N.E. Idenyi, ‘The Inhibition Characteristics of Brine on the Corrosion Susceptibilty of Al-Zn Alloy Systems,’ Information Technology Journal, vol.7, no. 2, pp. 237-241, 2007.

S. Vuelvas, S. Valdez, J. G. Gonzalez-Rodriguez, “Effect of Mg and Sn Addition on the Corrosion Behavior of an Al-Mn Alloy in 0.5 M H2SO4â€, Int. J. Electrochem. Sci., vol.7, pp. 4171 – 4181, 2012.

O. Lunder, T. Kr Aune, and K. Nisancioglu, "Effect of Mn additions on the corrosion behavior of mould-cast magnesium ASTM AZ91," Corrosion, vol. 43, no. 5, pp. 291-295, 1987.

N.E. Idenyi, S.I. Neife and U. Uzor, ‘The Corrosion Behaviour of Recrystalized Mild Steel in Various Tetraoxosulphate (vi) Acid [H2SO4] Concentrations’, J. Corrosion Sci. Tech., vol.1, no.1, pp. 54-55, 2004.

M.G. Fontana, 1987. Corrosion Engineering, 3rd Edition, New York, NY, McGraw-Hill Book Company, pp. 229237 1987.

M.N.C. Ijomah, Elements of Corrosion and Protection Theory, Auto Century Publishing Co. Ltd, Enugu, pp.112-126, 1991.

M. Reffass, C. Berziou, C. Rébéré, A. Billard, and J. Creus, "Corrosion behaviour of magnetron-sputtered Al 1− x–Mnx coatings in neutral saline solution," Corrosion Science, vol. 52, no. 11, pp.3615-3623, 2010.

H. Krawiec, S. Zbigniew, and V. Vignal, "Influence of applied strain on the micro-structural corrosion of AlMg2 as-cast aluminium alloy in sodium chloride solution," Corrosion Science, vol. 65, pp.387-396, 2012.

R. Arrabal, B. Mingo, A. Pardo, M. Mohedano, E. Matykina, and I. Rodríguez, "Pitting corrosion of rheocast A356 aluminium alloy in 3.5 wt.% NaCl solution," Corrosion Science, vol. 73, pp. 342-355, 2013.

G. Rossana, M. A. Baker, J. E. Castle, B. Dunn, and J. F. Watts, "Localized corrosion of a 2219 aluminium alloy exposed to a 3.5% NaCl solution," Corrosion Science, vol. 52, no. 9, pp. 2855-2866, 2010.

A. .I. Onen, B. T. Nwufo, E. E. Ebenso, and R. M. Hlophe, "Titanium (IV) oxide as corrosion inhibitor for aluminium and mild steel in acidic medium," International Journal of Electrochemical Science, vol. 5, pp. 1563-1573, 2010.

A.A. Mohammed, S.S. Abd EI-Rehim, E.E.F El-Sherbini, O.A. Hazzazi, and M. N. Abbas, "Polyacrylic acid as a corrosion inhibitor for aluminium in weakly alkaline solutions. Part I: Weight loss, polarization, impedance EFM and EDX studies," Corrosion Science, vol. 51, no. 3, pp. 658-667, 2009.

V. Ladislav, M. Kliškić, and S. Gudić, "Application of phenolic acids in the corrosion protection of Al-0.8 Mg alloy in chloride solution," Int. J. Electrochem. Sci., vol.4, pp.1568-1582, 2009.

A.Y. El-Etre, "Inhibition of aluminum corrosion using Opuntia extract," Corrosion science, vol.45, no. 11, pp. 2485-2495, 2003.

S.A. Umoren, I. B. Obot, E. E. Ebenso, and N. O. Obi-Egbedi, "The Inhibition of aluminium corrosion in hydrochloric acid solution by exudate gum from Raphia hookeri" Desalination, vol. 247, no. 1, pp.561-572, 2009.

A.B. Bouyanzer, Hammouti, and L. Majidi, "Pennyroyal oil from Mentha pulegium as corrosion inhibitor for steel in 1M HCl," Materials Letters, vol.60, no. 23, pp. 2840-2843, 2006.

M. Znini, L. Majidi, A. Bouyanzer, J. Paolini, J-M. Desjobert, J. Costa, and B. Hammouti, "Essential oil of Salvia aucheri mesatlantica as a green inhibitor for the corrosion of steel in 0.5 M H2SO4," Arabian Journal of Chemistry, vol. 5, no. 4, pp.467-474, 2012.

P.A. Nwofe, "Waste management and environmental sustainability-A case study of selected cities in Ebonyi State," Cont. J. Env. Sci., vol. 7, no. 1, pp.20-28, 2013.

P.A. Nwofe, "Comparative Analysis Of Domestic Energy Use in Nigeria," Continental Journal of Renewable Energy, vol. 4, no. 1, pp.7-17, 2013.

P.A. Nwofe, "Determination of the Generation rate of solid waste in Abakaliki Metropolis, Ebonyi State, Nigeria," Continental Journal of Environmental Sciences, vol. 7, no. 2, pp. 1-3, 2013.

K. R. Baldwin, R. I. Bates, R. D. Arnell, and C. J. E. Smith. "Aluminium-magnesium alloys as corrosion resistant coatings for steel," Corrosion science, vol.38, no. 1, pp.155-170, 1996.

P.A. Nwofe, "Waste Resources and Climate Change: Implications and Mitigation," International Journal of Science and Research, vol. 3, no. 9, pp. 1602-1606, 2014.

Patrick Akata Nwofe, "Management and Disposal of Municipal Solid Wastes in Abakaliki Metropolis, Ebonyi State, Nigeria," International Journal of Scientific Research in Environmental Sciences, vol.3, no. 3, pp.107-118, 2015.

A. K. Chandler, Marine and Offshore Corrosion, Betterworth and Co. (Publishers) Ltd, 1985.

W.D. Callister, Materials Science and Engineering- An Introduction, Ney York, John Wiley and Sons Inc., 1996.

L. Vrsalovic, M. Kliskic, S. Gudic, “Aplication of phenolic acids in the corrosion protection of Al-0.8Mg alloy in chloride solution†International Journal of Electrochemical Science, vol. 4, no. 11, pp.1568-1582, 2009.

K.R. Baldwin, R.I. Bates, R.D. Arnell, C.J.E. Smith, “Aluminium-magnesium alloys as corrosion resistant coatings for steel,†Corros.ion Science, vol. 38, no. 1, pp. 155-170, 1996.

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Published

2015-10-26

How to Cite

Effects of Manganese Addition on the Corrosion Behaviour of Aluminium Alloys in Different Media. (2015). Asian Journal of Applied Sciences, 3(5). https://ajouronline.com/index.php/AJAS/article/view/3158

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