Corrosion Inhibition and Quantum Mechanical Studies of Galvanized Steel Sheets in Chloride Environment
Keywords:
antibiotics, hydrogen permeation, corrosion inhibitors, green inhibitionAbstract
The corrosion inhibition of galvanized steel (GI steel)sheets  in 5% NaCl with Esomeprazole (EPZ) as green inhibitor has been reported  by Mass  loss, Potentiodynamic polarization, electrochemical impedance spectroscopy ,  hydrogen permeation and quantum mechanical  studies. All these techniques reveal that the EPZinhibits the corrosion of galvanized steel in 5% NaCl medium.Polarization studies indicated that inhibitors are acted as mixed type inhibitor. The adsorption of the compounds on galvanized steel surface follows Langmuir adsorption isotherm.
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References
El-Sayed M. Sherif, A. A. Almajid, A. K. Bairamov, Eissa Al-Zahrani, “A comparative Study on the Corrosion of Monel-400 in Aeratedand Deaerated Arabian Gulf Water and 3.5% Sodium ChlorideSolutionsâ€, Int. J. Electrochem. Sci., vol. 7,pp. 2796-2810, 2012.
YadavA.P., KatayamaH., NodaK., MasudaH., NishikataA., TsuruT., “Surface Potential Distribution over a Zinc/Steel Galvanic Couple Corroding under Thin Layer of Electrolyteâ€, Electrochem. Acta.,vol. 52, pp. 3121-3129, 2007.
AminM.A., HassanH.H., El RehimS.S.A., “On the role of NO2- ions in passivity breakdown of Znin deaerated neutral sodium nitrite solutions and the effect of some inorganic inhibitors potentiodynamic polarization, cyclic voltammetry, SEM and EDX studiesâ€, Electrochim. Acta, vol. 53,pp. 2600–2609, 2008.
Lin B.L., Lu J.T., Kong G., “Effect of molybdate post-sealing on the corrosion resistance of zinc phosphate coatings on hot-dip galvanized steelâ€, Corros. Sci.,vol.50, pp. 962-967, 2008.
Bajat, J.B., Stankovic, S., Jokic, B.M., Stevanovic, S.I., “Corrosion stability of Zn-Co alloys deposited from baths with high and low Co content - The influence of deposition current density. Surface and Coatings Technologyâ€, vol. 204, pp. 2745-2753, 2010.
Kartsonakis, I.A.,Balaskas, A.C.,Koumoulos, E.P.,Charitidis, C.A.,Kordas, G.C., “Incorporation of ceramic nano containers into epoxy coatings for the corrosion protection of hot dip galvanized steelâ€, Corros. Sci., vol. 57, pp. 30-41, 2012.
Zhang, X.G., “Corrosion of zinc and zinc alloys, Corrosion: Materialsâ€, ASM Handbook, pp.402-406, 2005.
Chenghao Liang, Peng Wang, Bo Wu, Naibao Huang, “Inhibition of copper corrosion by self-assembled monolayers of triazole derivative in chloride-containing solutionâ€, J Solid State Electrochem, vol. 14, pp.1391-1399, 2010.
Shukla SK, Quraishi MA., “Cefalexin drug: a new and efficient corrosion inhibitor for mild steel in hydrochloric acid solutionâ€, Mater Chem Phys., vol.120, pp.142–147, 2010.
Eddy, N. O. and Ebenso, E. E. (2008), “Adsorption and inhibitive properties of ethanol extract of Musa sapientumpeels as a green corrosion inhibitor for mild steel in H2SO4â€, African J. of Pure & Applied Chem.,vol. 2, no. 6, pp. 1-9, 2010.
Ambrish Singh, Ishtiaque Ahamed, Singh VK, Mumtaz Ahamed Quaraishi, “Inhibition effect of environmentally benign Karanj (Pongamiapinnata) seed extract on corrosion of mild steel in hydrochloric acid solutionâ€, J Solid State Electrochem., vol. 15, no. 6, pp. 1087-1097, 2011.
Quraishi, M. A. and Khan, S., “Inhibition of mild steel corrosion in sulfuric acid solution by thiadiazolesâ€, J. Appl. Electrochem., vol. 36, pp. 539-544, 2006.
Khaled KF, Mohamed, Hamed NH, Abdel-Azim KM, Abdelshafi NS, “Inhibition of copper corrosion in 3.5% NaCl solutions by a new pyrimidine derivative: electrochemical and computer simulation techniquesâ€, J Solid State Electrochem., vol. 15, pp. 663-673, 2011.
Hasanov, R., Sadikoglu, M. and Bilgic, S., “Electrochemical and Quantum Chemical Studies of Some Schiff Bases on the Corrosion of Steel in H2SO4â€, Applied Surface Science, vol. 253, pp. 3913-3921, 2007.
Umoren SA, Ying Li, Wang FH, “Effect of polyacrylic acid on the corrosion behaviour of aluminium in sulphuric acid solutionâ€, J Solid State Electrochem., vol. 14, pp. 2293-2305, 2010.
Bouklah M, Hammouti B, LagreneeM, Bentiss F, “Thermodynamic properties of 2,5-bis(4-methoxyphenyl)-1,3,4-oxadiazole as a corrosion inhibitor for mild steel in normal sulfuric acid mediumâ€, Corros. Sci.,vol. 48, pp. 2831-2842, 2006.
Abdallah M, “Rhodanineazosulpha drugs as corrosion inhibitors for corrosion of 304 stainless steel in hydrochloric acid solutionâ€, Corros. Sci., vol. 44, no.4, pp. 717-728, 2002.
Abdallah M, “Antibacterial drugs as corrosion inhibitors for corrosion of aluminium in hydrochloric solutionâ€, Corros. Sci., vol. 46, no.8, pp. 1981-1996, 2004.
El-Naggar MM, “Corrosion inhibition of mild steel in acidic medium by some sulfa drugs compoundsâ€, Corros. Sci., vol. 49, pp. 2226-2236, 2004.
Solmaz R, Kardas G, Yazici B, Erbil M, “Inhibition Effect of Rhodanine for Corrosion of Mild Steel in Hydrochloric Acid Solutionâ€, Protection of Metals, vol. 41, pp. 581-585, 2005.
Joseph Raj Xavier, Rajendran Nallaiyan, “Corrosion inhibitive properties and electrochemical adsorption behavior of some piperidine derivatives on brass in natural sea waterâ€, J Solid State Electrochem., vol.16, pp. 391-402, 2012.
El-Dissouky A, El-Bindary AA, El-Soubati AZ, Hilali AS, “Structural and models of dioxouranium(VI) with rhodanineazodyes – Vâ€, Spectrochim. Acta, vol. 57, pp. 1163-1170, 2001.
Roberta de Oliveira Ramos, Alice Battistin, Reinaldo Simoes Goncalves, “Alcoholic Mentha extracts as inhibitors of low-carbon steel corrosion in aqueous mediumâ€, J Solid State Electrochem., vol. 16, pp.747-752, 2012.
Eddy, N. O., Odoemelam, S. A. and Mbaba, A. J. “Inhibition of the corrosion of mild steel in HCl by sparfloxacinâ€, Afr. J. Pure & Appl. Chem., vol.2, no.12, pp.132-138, 2008.
Gokhan Gece, “Drugs: A review of promising novel corrosion inhibitorsâ€, Corros. Sci.,vol. 53, pp. 3873-3898, 2011.
Hari Kumar, S. and Karthikeyan, S., “The influence of ampicillin on the corrosioninhibition of mild steel in 1n hydrochloric acid solutionâ€, International Journal of Current Research and Review, vol. 4, pp. 96–104, 2012.
Muralidharan S, Madhavan K, Karthikeyan S, Venkatakrishna Iyer S, “Influence of anions on corrosion inhibition and hydrogen permeation through mild steel in acidic solutions in the presence of p-tolylthioureaâ€, vol. 9, no.1, pp. 68-73, 2002.
Bentiss, F., Lagrenee, M., Traisnel, M., Hornez, J.C., “The corrosion inhibition of mild steel in acidic media by a new triazole derivativeâ€, Corros. Sci., vol. 41, pp. 789–803, 1999.
Ashassi-Sorkhabi H, Shaabani B, Seifzadeh D, “Effect of some pyrimidinic Shciff bases on the corrosion of mild steel in hydrochloric acid solutionâ€, Electrochim Acta, vol. 50, no. 16, pp. 3446-3452, 2005.
Karthikeyan S, Neelakandan MA, “Diacetylthiourea as an inhibitor for the corrosion of mild steel in acidic solutionsâ€, J Electrochem. Soc India, vol. 56, pp. 151-157.
Devanathan MAV, Stachurski Z, “The adsorption and diffusion of electrolytic hydrogen in Palladiumâ€, Proc. Roy Soc. A, vol. 270:90, 1962.
Shukla SK, Quraishi MA, “4-Substituted anilinomethylpropionate: New and efficient corrosion inhibitors for mild steel in hydrochloric acid solutionâ€, Corros. Sci., vol. 51, no. 9, pp. 1990-1997, 2009.
Madhavan K, Quaraishi MA, Karthikeyan S,Venkatakrishna Iyer S, “1, 2, 4, 5 Tetrazospiro (5, 4) decane-3-thione as an inhibitor for the corrosion of mild steel in acidic solutionsâ€, J Electrochem. Soc India, vol. 49, pp. 183-188, 2000.
Madhavan K, Karthikeyan S, Venkatakrishna IyerS, “Diphenylthiourea as an inhibitor for the corrosion of mild steel in acidic mediaâ€, J. Electrochem. Soc India, vol. 50, pp. 37, 2001.
Eddy NO and Ebenso EE, “Corrosion Inhibition and Adsorption Characteristics of Tarivid on Mild Steel in H2SO4â€, E-J Chem., vol. 7, pp. 442-448, 2010.
Eddy NO, Odoemelam SA, Mbaba AJ, “Inhibition of the corrosion of mild steel in HCl by sparfloxacinâ€, African Journal of Pure and Applied Chemistry, vol. 2, pp. 132-138.
Lebrini M, Traisnel M, Lagrenee M, Mernari B, Bentiss F, “Inhibitive properties, adsorption and a theoretical study of 3,5-bis(n-pyridyl)-4-amino-1,2,4-triazoles as corrosion inhibitors for mild steel in perchloric acidâ€, Corros. Sci., vol. 50, pp. 473-479, 2008.
Morad MS, Kamal El-Dean AM, “2,2’-Dithiobis (3-Cyano-4,6-Dimethylpyridine): A New Class of Acid Corrosion Inhibitors for Mild Steel,†Corros.Sci., vol. 48, no. 11, pp 3398-3412, 2006.
Tang L, Mu G, Liu G, “The effect of neutral red on the corrosion inhibition of cold rolled steel in 1.0 M hydrochloric acidâ€, Corros. Sci., vol. 45, pp. 2251-2262, 2003.
Khamis E, Belluci F, Latanision R. M, El-Ashry E.S.H, “Acid corrosion inhibition of nickel by 2-(tri-phenosphoranylidene) succinic anhydrideâ€, Corrosion, vol. 47, pp. 677–686, 1991.
Geler, E.,Azambuja, D. S.,“Corrosion inhibition of copper in chloridesolutions by pyrzoleâ€, Corros. Sci., vol. 42, pp. 631-643, 2000.
Abiola OK, “Adsorption of 3-(4-amino-2-methyl-5-pyrimidylmethyl)-4-methylthiazolium chloride on mild steelâ€, Corros. Sci.,vol. 48, pp. 3078-3090, 2006.
Singh AK, Quaraishi MA, “ Inhibitive effect of diethylcarbamazine on the corrosion of mild steel in hydrochloric acidâ€, Corros. Sci., vol. 52, pp. 1529-1535, 2010.
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