Effects of Chloride Bath Concentration on Structural and Magnetic Properties of Electroplated NiFeCr Thin Films

Authors

  • R. Kanagaraj Department of Physics, Greentech College of Engineering for women, Attur, Salem-636108, Tamil Nadu, India
  • R. Kannan
  • S. Ganesn
  • S. K. Muthukumar

Keywords:

NiFeCr films, Chloride bath, Microstructure, Coercivity, Saturationmagnetization and Adhesion.

Abstract

Electrodeposition of NiFeCr thin ï¬lms have been successfully carried out from chloride bath at a constant current density (1 A/dm2) by varying the chloride bath concentration (0.1, 0.2, 0.3 and 0.4mol/lit). The surface morphology, microstructure and magnetic properties such as coercivity, saturation magnetization were investigated for electroplated NiFeCr thin ï¬lms. The SEM micrographs of the electrodeposited ï¬lms from the chloride bath concentration of 0.4 mol/lit have no micro cracks and also the ï¬lms have more uniform surface morphology as compared with the film coated from lower concentration. The predominant peaks in X-ray diffraction pattern reveal the crystalline nature of the ï¬lm and found to have BCC structure. From the VSM results of the electrodeposited NiFeCr thin ï¬lms, the various magnetic analysis such as coercivity, saturation magnetization were calculated. The hardness and adhesion of the electroplated ï¬lms with substrate were also investigated. Reasons for variation in magnetic properties and structural characteristics were discussed.

Author Biography

  • R. Kanagaraj, Department of Physics, Greentech College of Engineering for women, Attur, Salem-636108, Tamil Nadu, India
    Department of Physics, Greentech College of Engineering for women, Attur,Salem-636108, Tamil Nadu, India

References

. Daheum Kim., Park, D.Y., Yoo, B.Y., Sumodjo, P.T.A. and Myung N.V. “Magnetic properties of nanocrystalline iron group thin ï¬lm alloys electrodeposited from sulfate and chloride bathsâ€, ElectrochimicaActa., Vol. 48, pp.819–830, 2003.

. Bonkeup Koo, BongyoungYoo. Surf Coat Tech. 205, 740 (2010).

. B.Y.Yoo, S.C. Hernandez, D.Y. Park, N.V.Myung. Electrochim.Acta. 51, 6346 (2006).

. Esther, P., Joseph Kennady, C., Saravanan, P. and Venkatachalam, T. “Structural and magnetic properties of electrodeposited ni-fe-w thin filmsâ€, J. Non Oxide Glas., Vol.1, No. 3, pp.301, 2009.

. R.Kanagaraj, R. Kannan, S. Ganesan, and P.Esther, “Effect of bath temperature onstructural and magneticproperties ofelectrodeposited NiFeCr thin films,â€Journal of Optoelectronics and Advanced Materials, vol. 17, pp. 139 – 144, 2015

. Kannan, R., Ganesan, S., Balasubramanian, V. and Rajeswari, M. “Diammonium citrate concentration on structural and magnetic properties of nano structured NiFeWS alloy thin filmsâ€, Advanced Science Focus, Vol. 1, No. 1, doi:10.1166/asfo.2013.1026, pp.1- 7, 2013.

. M. RAJESWARI, S. GANESAN, T. M. SELVAKUMARI, R. KANNAN , “Characterization of electrodeposited nanocrystalline Ni-Mn thin films for MEMS applicationsâ€, Vol. 16, No. 5-6, May - June 2014, p. 640 – 644.

. Kannan, R,Kanagaraj, R &Ganesan, S 2013 ‘Influence of Tri Sodium Citrate Bath Concentration on the Electrodeposition of NiFeWS Thin Films’, Journal of Ovonic Research, vol.9, no.2, pp.45-54, March - April 2013.

. T.M.Selvakumari, P.Muthukumar, S.Ganesan. Dig J Nanomater Bios. 5,(4), 903- (2010).

. Ohgai, T., Tanaka, Y. and Fujimaru, T. “Soft magnetic properties of Ni–Cr and Co–Cr alloy thin ï¬lms electrodeposited from aqueous solutions containing trivalent chromium ions and glycineâ€, J ApplElectrochem., Vol.42, pp. 893–899, 2012.

. Kannan, R., Ganesan, S. and Selvakumari, T.M. “Synthesis and characterization of nano crystalline NiFeWS thin films in diammonium citrate bathâ€, Digest journal of nanomaterials and biostructures, Vol.7, No.3, pp.1039 -1050, 2012.

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Published

2015-08-17

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How to Cite

Effects of Chloride Bath Concentration on Structural and Magnetic Properties of Electroplated NiFeCr Thin Films. (2015). Asian Journal of Applied Sciences, 3(4). https://ajouronline.com/index.php/AJAS/article/view/2835

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