Photo-electronic Measurement of Film Thickness for the Sulphonation of Methyl Esters in Falling Film Reactors
Keywords:
Film thickness, Falling film reactors, optical sensorsAbstract
An optical-electronic system was developed for the determination of film thicknesses in falling film reactors and applied to the analysis of methyl esters sulphonation. Calibration and experimental tests were performed to obtain a correlation between the film thickness (d ) and the measured Voltage (V) of the photo electronic cell. Voltage sensing and film thickness calculations were found to be highly dependent on the position of the sensing device from the reactor inlet and slightly dependant on the gas flow rate under the range of experimental values tested. This optical-electronic system allows a real-time quantitative description of the dynamic behavior of the undulations in the falling film.
References
Castaneda, W., and A. Rivas, 2004 Dimensionamiento de un sistema para la sulfonación de ésteres metılicos del aceite de palma a nivel laboratorio. Universidad Nacional de Colombia, Bogotá.
Chu, K. J., and A. E. Dukler, 1974, Statistical Characteristics of Thin, Wavy Films .2. Studies of Substrate and Its Wave Structure: Aiche Journal, v. 20, p. 695-706.
Chu, K. J., and A. E. Dukler, 1975, Statistical Characteristics of Thin, Wavy Films .3. Structure of Large Waves and Their Resistance to Gas-Flow: Aiche Journal, v. 21, p. 583-593.
Diaz, L., H. Zea, and F. Sanchez, 2013, Hydrodynamic Effects Asociated to Methyl Ester Sulphonation in Falling Film Reactors: Dyna-Colombia, v. 80, p. 44-50.
Gutierrez, J., C. Mansteixido, and J. Costalopez, 1988, Improved Mathematical-Model for a Falling Film Sulfonation Reactor: Industrial & Engineering Chemistry Research, v. 27, p. 1701-1707.
Karimi, G., and M. Kawaji, 1999, Flow characteristics and circulatory motion in wavy falling films with and without counter-current gas flow: International Journal of Multiphase Flow, v. 25, p. 1305-1319.
Kil, S. H., S. S. Kim, and S. K. Lee, 2001, Wave characteristics of falling liquid film on a vertical circular tube: International Journal of Refrigeration-Revue Internationale Du Froid, v. 24, p. 500-509.
Killion, J. D., and S. Garimella, 2001, A critical review of models of coupled heat and mass transfer in falling-film absorption: International Journal of Refrigeration-Revue Internationale Du Froid, v. 24, p. 755-797.
Stein, W., and H. Baumann, 1975, Alpha-Sulfonated Fatty-Acids and Esters - Manufacturing Process, Properties, and Applications: Journal of the American Oil Chemists Society, v. 52, p. 323-329.
Talens-Alesson, F. I., 2000, The effect of superficial gas velocity on wavy films and its use in enhancing the performance of falling film reactors: Chemical Engineering & Technology, v. 23, p. 629-632.
Telles, A. S., and A. E. Dukler, 1970, Statistical Characteristics of Thin, Vertical, Wavy, Liquid Films: Industrial & Engineering Chemistry Fundamentals, v. 9, p. 412-&.
Torres, J., 2009, Producción de alfa sulfo-estearato de metilo en un reactor de pelÃcula descendente, PhD Thesis, Universidad Nacional de Colombia, Bogotá, Colombia.
Xu, Z. F., B. C. Khoo, and N. E. Wijeysundera, 2008, Mass transfer across the falling film: Simulations and experiments: Chemical Engineering Science, v. 63, p. 2559-2575.
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