Thermodynamic and Transport Properties of Aromatic Amine with Ketone in Nonpolar Solvent at 303.15, 308.15 and 313.15K
Keywords:
adiabatic compressibility, free length, free volume, internal pressure, Gibbs free energy, relaxation time, excess parametersAbstract
The ultrasonic velocity(U), density(Ï) and viscosity(η) measurements were carried out for the three organic ternary mixtures of aniline+1,4-dioxan+propanone , aniline+1,4-dioxan+butanone and + aniline+1,4-dioxan+Methyl Iso Butyl Ketone at 303.15, 308.15 and 313.15 K. From the measured value the derived acoustic and thermodynamic parameters namely adiabatic compressibility(β), free length(LF), free volume(VF), internal pressure(Ï€i) ,Gibbs free energy (ΔG) were evaluated. In addition, excess values of certain above parameters were also calculated. The above parameters were used to discuss the presence of significant interactions between the component molecules in the ternary mixtures. Observed excess values in the mixture indicate the existence of strong interactions in the system.
References
Palaniappa L et.al. Ind.J.phys, 75 ,515-518, 2001.
Rajendranaidu G & Ramachandranaidu, Ind.J.pure & Appl.phys, 22, 207-209,1984.
Ali A, Tiwari K, Nain A K & V. Charkravarthy,Ind.J.phy,74B (5),351-355,2000.
Devadoss D, Thairiyaraja M & Palaniappan L, Ind.J.phys, 77B (6), 669-672,2003.
Sumathi T & Varalakshmi M, Ind.J.pure & Appl.phys, 50, 105-109,2012.
] Kannappan V& Jaya Shanthi R,Ultrasonic studies of induced dipole-dipole
Ind. J. Pure. Appl. Phys. 43, 750-754, 2005.
Miecznik P, Golebiewski Z & Mielcarek S, Fluid phase Equilibria, 41,221, 2004.
Vasantharani P, Balu L, Ezhilpavai R & Shailajha, Glob.J.Mole Sci, 4(1),
- 48, 2009.
Prabakar S, Rajagopal K, J.pure & Appl ultrasonic, 27,41-48,2005.
Miecznik P, Golebiewski Z & Mielcwerek S, Fluid phase Equilibria, 41,
, 221.
Bhandakkar V D, Chimankar O P & Power N R J. of Chemical & Pharmaceutical Res,
, 873-877,2010.
Madhu Rastogi, Aashees Awasthi, Manisha Guptha & J.P.Shukla. Ultrosonic
investigations of X-HO bond complexes. Ind J. Pure Appl. Phys., 40,256-263, 2002.
Surjit Singh Bhatti & Devinder Pal singh.Molecular association in some
n-butanol systems. Ind.J.Pure Appl.Phys.2,506-509,1983.
Kumar R ,Mahesh R, Shanmugapriyan B & Kannappan VInd.J.pure & Appl.phys, 50,
-640,2012.
Fort R J & Moore W R, Trans Faraday society, 62,1112,1966.
Palani et.al., Mat. Sci. Res. India.5 (2),367-374, 2008.
Ramammorthi K& Alwan S, Current Sci., 47,334,1978.
Fort R J & Moore W R, “Adiabatic compressibilities in binary liquid mixturesâ€,
Trans .Farad. Soc., 61,1965,2102-2110.
Archives of Physics Research, 2 (1), 254-261,2011.
]Palani R, Saravanan S & Kumar R , Rasayan J.Chem, 2,622-629,2009.
Fluid Phase Equilibria, 307 2 113-125.
Kinsler LE & Rray A R, Fundamental of Acoustic Wiley eastern, New Delhi,1989.
Hyder A & Nair A K, Indian journal of pure and applied Physics, 63, 7413,2000.
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