Comparative Evaluation of Metals and Heavy Metals in Some Yemeni Crude and Fuel Oil

Authors

  • Rokhsana M. Ismail University of Aden, Yemen
  • Fatima Sahleh Nagi University of Aden, Yemen

DOI:

https://doi.org/10.24203/ajas.v8i6.6384

Keywords:

crude, fuel oil, Mareb, Masila oil Sounah, Hijah, heavy metals

Abstract

Due to high importance of the crude oil to the modern society as a source of energy and as raw material for a wide chemical and petro chemical industries.

In this study we made assessment of metals and heavy metals  in some Yemeni crude, and fuel oils namely Mareb crude oil blend, Masila crude oil blend plus two samples from Sounah and Hijah oil fields in Masila basin.

Fifteen  metals and heavy metals were determined in above samples, but the most indicated were ( Na, K, Mg, ) and ( V, Co, Ni ) using ICP technique and atomic absorption spectroscopy .

The order of concentration of metals in Yemeni crude oils were as shown in figures:

Na < K < Co < Mg < V < Ni < Ca< Fe < Cd < Al< Zn < Cr < Cu < Pb < Mn.

In Fuel oil: Na < Co < V < Mg < K < Ni < Ca < Fe < Al < Cd < Zn < Cr< Pb < Mn < Cu.

Comparing concentrations of metals in studied sample, in general were less than in crude oil and fuel oil in many countries. That mean Yemeni crude and fuel oil are the best in quality.

The order of concentration of metals in Yemeni crude oils were as shown in figures:

Na < K < Co < Mg < V < Ni < Ca< Fe < Cd < Al< Zn < Cr < Cu < Pb < Mn.

In Fuel oil: Na < Co < V < Mg < K < Ni < Ca < Fe < Al < Cd < Zn < Cr< Pb < Mn < Cu.

Comparing concentrations of metals in studied sample, in general were less than in crude oil and fuel oil in many countries. That mean Yemeni crude and fuel oil are the best in quality.

 

References

Alrich J., hilner A. and Stark H., "Distribution of trace elements in crude oils from Southern Germany," Chemical Geology, vol. 48, 1985.

Altaban A., ( 1999 ), Spectroscopy Analysis for Metals and Heavy Metals in Syrian Crude Oil. Master thesis , University of Aleppo.

Alkiali A., Zuhair W., ( 1991). Chemistry & Technology of Petroleum. Universityof Aleppo publication , faculty of science.

Barbooti M. M, Al-Madfai S. H. and Al-Sammerrai D. A., "Thermogravimetric characterization of Quayarah heavy crude oils," Journal of Thermal Analysis, vol. 31, pp.253-260,1986.

Barbooti M., Al-Taee M.A. and. Qasim B. H, "Electrothermal atomic absorption spectrophotometric determination of V, Ni and Pb in hydrocarbons polluted Soils," Engineer, Technol, vol. 28, pp. 17-28, 2010.

Beydoun, Z. R. As-Saruri, M. and Baraba, R. S. 1996. Sedimentary basins of the Republic of Yemen: their: structural evolution and geological characteristics. Revue InstitutFrancaisPetrole, 51(6), 763-775.

Csato, I., A. Habib, K. Kiss, I. Kocz, Z. Kovacs, K. Lorincz, and K. Milota, 2001. Play concepts ofoil exploration inYemen: Oil and Gas Journal, 99, 68–74.

Dulama, I.D.., Popescu, I.V., Stihi, C., Radulescu, C., Cimpoca, Gh.V.,Toma, L.G., Stirbescu, R., Nitescu, O., Romanian Report on Physics, 64(4), 2012.

Ellis, A. C., Kerr, H. M., Cornwell, C. P. and Williams, D. O. 1996.A tectonostratigraphic framework for Yemen and its implication for hydrocarbon potential.Petroleum Geoscience, 2, 2942.

Hitchon B. and Filby R. H., "use of trace elements for classification of crude oils into families, examples from Alberta, Canada," American Association of Petroleum and Geologists (AAPG), pp. 838-849, 1984.

Holmes, C.W and Barnes, S.S (1977) Trace Metal Mineralogical Analysis of Suspended and Bottom Sediment. South Texas. U.S Burea of land Management.

NNPC/PTI (1987) The Petroleum Industry. An International Seminar Report, 4, 103-105.

Popescu, I.V., Frontasyeva, Stihi, C., Cimpoca, Gh.V., Radulescu C., Gheboianu, A., Oros, C., Vlaicu, Gh., Petre, C., Bancuta, I., Dulama I.D., Romanian Journal of Physics, 55(7-8), 8212010.

Popescu I.V., Frontasyeva M., Stihi C., CimpocaGh.V., Radulescu C., State G., Gheboianu A., Oros C., Cilicov, O., Bancuta, I., Dulama, I.D, Romanian Reports on Physics, 63, 1205, 2011.

Reynolds J. G., "Removal of Nickel and Vanadium from Heavy Crude Oils by Echange Reaction," Americal Chemical Society, Divisions of fuel Chemistry, vol. 49, pp. 79-80, 2004.

Redfern P., Jones J.A., The interior basins of Yemen—analysis of basin structure and stratigraphyin a regional plate tectonic context, Basin Res. 7 (1995) 337–356.

State, G., Popescu, Ion V., Gheboianu, A., Radulescu, C., Dulama, I., Bancuta, I., Stirbescu, R., Romanian Journal of Physics, 56(1-2), 2011.

Stanisley, P. (2002). Waste discharge during offshore Oil and Gas activity. Environmental Impact of the offshore Oil and Gas Industry. 31, 48-65.

Stihi, C., Radulescu, C., Busuioc, G., Popescu, I.V., Gheboianu, A., Ene, A., Romanian Journal of Physics, 56(1-2), 257, 2011.

United States Environmental Protection Agency (USEPA)(2002). Data quality review. EPA/540/R-02/506. National risk Management Laboratory. Office of Research and Development U.S Environmental Protection Agency

Valcarel, M.(2000) Principles of Analytical Chemistry, New York. Springer-Verlag BerlinHeidelberg.

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Published

2020-12-31

How to Cite

Ismail, R. M., & Nagi, F. S. (2020). Comparative Evaluation of Metals and Heavy Metals in Some Yemeni Crude and Fuel Oil. Asian Journal of Applied Sciences, 8(6). https://doi.org/10.24203/ajas.v8i6.6384