Synthesis of Carbon Nano Fibers: Fabrication and Characterization of Carbon Nano Fibers/rea-formaldehyde resin

Authors

  • Tanveer Ahmed Khan Najran University
  • Arun Gupta
  • S. S. Jamari
  • Pradeep Poddar

Keywords:

Wood Fibers, Urea-Formaldehyde, Carbon Nano Fibers

Abstract

This paper addresses fabrication of carbon nano fibers by pyrolysis of wood fibers and their dispersion in urea formaldehyde with an aim to optimize a stable carbon nano fibers/urea formaldehyde resin. All the resin hybrids were characterized with Fourier transform infrared spectroscopy (FTIR) and powder X-ray diffractometry (XRD), while the dispersion of carbon nano fibers particles was studied with Field Emission scanning electron microscopy (FESEM). Thermo gravimetric analysis (TGA) revealed that carbon nano fibers have little high effect in the thermal stability of the UF resin. From the TGA graph, it is observed that the thermal stability of the UF based carbon nano fibers is higher than UF only. The scanning micrographs provided evidence of the smoother surfaces in the UF resin made with carbon nano fibers. This was attributed to the better encapsulation of ï¬bers by the matrix polymer.

References

M. Dunky, Urea–formaldehyde (UF) adhesive resins for wood, Int. J. Adhes. Adhes. 18 (1998) 95–107.

B.-D. Park, E.-C. Kang, J.Y. Park, Differential scanning calorimetry of urea–formaldehyde adhesive resins, synthesized under different pH condi-tions, J. Appl. Polym. Sci. 100 (2006) 422–427.

Z. Que, T. Furuno, S. Katoh, Y. Nishino, Evaluation of three test methods in determination of formaldehyde emission from particleboard bonded with dif-ferent mole ratio in the urea–formaldehyde resin, Build. Environ. 42 (2007) 1242–1249.

R. Marutzky, in: A. Pizzi (Ed.), Wood Adhesives: Chemistry and Technology, vol. 2, Marcel Dekker, New York, 1986, p. 307.

B.D. Park, E.C. Kang, J.Y. Park, Effects of formaldehyde to urea mole ratio on thermal curing behavior of urea–formaldehyde resin and properties of parti-cleboard, J. Appl. Polym. Sci. 101 (2006) 1787–1792.

G.E. Myers, How mole ratio of UF resin affects formaldehyde emission and other properties: a literature critique, Forest Prod. J. 34 (1984) 35–41.

C.Y. Hse, X.Y. Xia, B. Tomita, Effects of reaction pH on properties and performance of urea–formaldehyde resins, Holzforschung 48 (1994) 527–532.

J.Y. Gu, M. Higuchi, M. Morita, C.Y. Hse, Synthetic conditions and chemical struc-tures of urea–formaldehyde resins. I. Properties of the resins synthesized by three different procedures, Mokuzai Gakkaishi 41 (1995) 1115–1121.

S. Tohmura, C.Y. Hse, M. Higuchi, Formaldehyde emission and high-temperature stability of cured urea–formaldehyde resins, J. Wood Sci. 46 (2000) 303–309.

B. Tomita, S. Hatono, Urea–formaldehyde resins III. Constitutional characteri-zation by carbon-13 Fourier transform NMR spectroscopy, J. Appl. Polym. Sci. 16 (1978) 2509–2525.

J. Dutkiewicz, Preparation of cured urea–formaldehyde resins of low formalde-hyde emission, J. Appl. Polym. Sci. 29 (1984) 45–55.

A. Pizzi, Advanced Wood Adhesives Technology, Marcel Dekker, New York, 1994.

G.B. Du, Application of mineral filler of urea formaldehyde resin as plywood adhesive, China Adhes. 4 (1995) 39–42.

E. Markessini, Formaldehyde emissions from wood-based panels and ways to reduce them, Monument Environ. 2 (1994) 57–64.

J.H. Williams, Hydrolytically Stable Urea–Formaldehyde Resins and Process for Manufacturing Them, Louisville, Ohio, 1983, US Patent 4410685.

Zheng, Y. Zheng, R. Ning, Effects of nanoparticles SiO2 on the performance of nanocomposites, Mater. Lett. 57 (2003) 2940–2944.

I.M. Arafa, M.M. Fares, A.S. Barham, Sol–gel preparation and properties of inter-penetrating, encapsulating and blend silica-based urea–formaldehyde hybrid materials, Eur. Polym. J. 40 (2004) 1477–1487.

Tanveer Ahmed Khan, Arun Gupta, Saidatul Shima Jamari, Rajan Jose, Mohammed Nasir and Anuj Kumar, “Synthesis and Characterization of Carbon Fibers and its Application in Wood Composite, BioResources, 8(3), 4171–4184,2013.

A. Gupta, K.V. Sharma, R.M. Yunus, & A. Kumar, U.S. Patent No. 8,435,430. Washington, DC: U.S. Patent and Trademark Office (2013).

[19] A. Gupta, K.V. Sharma, & A. Kumar, Thermal and mechanical properties of urea-formaldehyde (UF) resin combined with multiwalled carbon nanotubes (MWCNT) as nanofiller and fiberboards prepared by UF-MWCNT. Holzforschung. (2013) DOI: 10.1515/hf-2014-0038

D. Bikiaris, V. Karavelidis, G. Karayannidis, A new approach to prepare poly(ethylene terephthalate)/silica nanocomposites with increased molecular weight and fully adjustable branching or crosslinking by SSP, Macromol. Rapid Commun. 27 (2006) 1199–1205.

S.S. Jada, The structure of urea–formaldehyde resins, J. Appl. Polym. Sci. 35 (1988) 1573–1592.

B.C. Smith, Infrared Spectral Interpretation: A Systematic Approach, CRC Press, Boca Raton, 1998.

M.O. Edoga, Comparative study of synthesis procedures for urea–formaldehyde resins (Part I), Leonardo Elect. J. Pract. Tehnol. 9 (2006) 63–80.

S. Samarzija-Jovanovic, V. Jovanovic, S. Konstantinovic, G. Markovic, M. Marinovic-Cincovic, Thermal behavior of modified urea–formaldehyde resins, J. Therm. Anal. Calorim. 104 (2011) 1159–1166.

G. Camino, L. Operti, L. Trossarelli, Mechanism of thermal degradation of urea-formaldehyde polycondensates, Polym. Degrad. Stab. 5 (1983) 161–172.

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Published

2014-12-15

How to Cite

Synthesis of Carbon Nano Fibers: Fabrication and Characterization of Carbon Nano Fibers/rea-formaldehyde resin. (2014). Asian Journal of Applied Sciences, 2(6). https://ajouronline.com/index.php/AJAS/article/view/2141

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